Description
Title: Investigation of Vinyl Ether and Its Isomers’ Electron Scattering
Abstract: In-depth theoretical research on electron scattering from vinyl ether and its isomers is presented in this article. A complicated optical potential approach is used to solve the electron-molecule quantum collision problem. Different cross sections were obtained for energies ranging from the target’s ionization threshold to 5 keV from the solution of the Schrödinger equation corresponding to this scattering problem. The non-spherical and complex structure is addressed using a multi-center group additivity approach. Additionally, a geometrical screening correction is used to make up for the results’ overestimation caused by the overlap of electron charge densities. We discovered a fascinating relationship between the target molecule’s ionization energy and maximum ionization cross section with polarizability. This article reports on the fitting of the total cross section as a function of the incident electron energy. For vinyl ether and its isomers, a correlation between the target’s effective diameter and the projectile’s wavelength at maximum ionization energy has also been reported. The information provided here will be helpful for mass spectrometry, chemical databases, and biomedical applications on military ranges. Due to their presence in Mars’ atmosphere, the cross sections are also crucial when modeling its atmosphere. The total scattering cross sections for electron impacts are used to estimate the gas-kinetic radius and van der Waals coefficients. Additionally, the present study predicts that isomeric effects will be present in the cross section.
Keywords: electron scattering; elastic cross section; inelastic cross section; vinyl ether; isomeric effect; optical potential method
Paper Quality: SCOPUS / Web of Science Level Research Paper
Subject: Physics
Subject Category: Atomic and Molecular Physics, and Optics
Writer Experience: 20+ Years
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